Fedunov R.G., Ivanov A.I. The influence of the energy parameters of donor-acceptor complexes on transient absorption dynamics of charge transfer state

Fedunov Roman Gennadievich
 
Candidate of Physical and Mathematical Sciences, Senior Lector, Department of Theoretical Physics and Wave Phenomena, Volgograd State University
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Prospect Universitetsky, 100, 400062 Volgograd, Russian Federation
 
Ivanov Anatoliy Ivanovich
 
Doctor of Physical and Mathematical Sciences, Professor, the Head of Department of Theoretical Physics and Wave Phenomena, Volgograd State University
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Prospect Universitetsky, 100, 400062 Volgograd, Russian Federation

Abstract. Transient absorption dynamics and the charge transfer state depopulation dynamics of the donor-acceptor complexes have been calculated at the polar solvent. The influence of the reorganization energy and the free energy gap on the transient absorption rate decay has been analyzed for the electron transition from the charge transfer state to the high excited state. For a solvent with the single relaxation mode it has been shown that the variation of the carrier frequency of the pump pulse does not affect the transient absorption dynamics and changes the charge transfer state depopulation dynamics.

Key words: transient absorption dynamics, pump – probe experiment, charge recombination, donor-acceptor complexes, high excited states.

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The influence of the energy parameters of donor-acceptor complexes on transient absorption dynamics of charge transfer state by Fedunov R.G., Ivanov A.I. is licensed under a Creative Commons Attribution 4.0 International License.

Citation in English: Science Journal of Volgograd State University. Mathematics. Physics. №2 (15) 2011 pp. 110-117

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