Mikhailova E.A., Mikhailova V.A. Effect of Vibrational Transitions on the Nonthermal ChargeTransfer Probability

https://doi.org/10.15688/mpcm.jvolsu.2019.2.7

Elena Alexandrovna Mikhailova
Candidate of Physical and Mathematical Sciences, Associate Professor,
Department of Theoretical Physics and Wave Processes,
Volgograd State University
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Prosp. Universitetsky, 100, 400062 Volgograd, Russian Federation

Valentina Alexandrovna Mikhailova
Doctor of Physical and Mathematical Sciences,
Head of Department of Theoretical Physics and Wave Processes,
Volgograd State University
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https://orcid.org/0000-0002-9123-0391
Prosp. Universitetsky, 100, 400062 Volgograd, Russian Federation

Abstract. In the framework of the stochastic approach, the effect of transitions between the vibrational sublevels of products on the ultrafast dynamics of “hot” (non-thermal) electron transfer in donor — acceptor complexes dissolved in a polar medium has been investigated. An analytical expression has been obtained for the probability of electron transfer, which takes into account the transition between the vibrational states of products and the mutual influence of sinks. Quantitative estimates of the scale of the mutual influence of sinks on the probability of electron transfer are made.

Key words: charge recombination, photoinduced reaction, charge transfer, intramolecular vibrational relaxation, nonequilibrium of nuclear system.

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Effect of Vibrational Transitions on the Nonthermal ChargeTransfer Probability by Mikhailova E.A., Mikhailova V.A. is licensed under a Creative Commons Attribution 4.0 International License.

Citation in English: Mathematical Physics and Computer Simulation. Vol. 22 No. 2 2019, pp. 76-85

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