Rogozina M.V., Ionkin V.N., Ivanov A.I. Modeling the kinetics of ultrafast charge separation and charge recombination in excited zinc-porphyrins derivetes

 
Rogozina Marina Viktorovna
 
Post-Graduate Student, Department of Theoretical Physics and Wave Phenomena,Volgograd State University
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Prospect Universitetsky, 100, 400062 Volgograd, Russian Federation
 
Ionkin Vladimir Nikolaevich
 
Candidate of Physical and Mathematical Sciences, Assistant Professor of Department of Theoretical Physics and Wave Phenomena,Volgograd State University
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Prospect Universitetsky, 100, 400062 Volgograd, Russian Federation
 
Ivanov Anatoliy Ivanovich
 
Doctor of Physical and Mathematical Sciences, Professor, the Head of Department of Theoretical Physics and Wave Phenomena, Volgograd State University
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Prospect Universitetsky, 100, 400062 Volgograd, Russian Federation

Abstract. The intramolecular charge separation from the second singlet excited state of Zn-porphyrin derivatives and subsequent charge recombination into the first singlet excited state have been explored. In the framework of the model considered the influence of the medium reorganization energy and dynamic properties of the solvent on the yield of products are investigated. Simulations of the chargeseparated state population dynamics allow reproducing the experimentally observed features of the kinetics in Zn-porphyrin derivatives.

Key words: second excited state, photoinduced electron transfer, nonthermal transitions, solvent relaxation, molecular switch.

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Modeling the kinetics of ultrafast charge separation and charge recombination in excited zinc-porphyrins derivetes by Rogozina M.V., Ionkin V.N., Ivanov A.I. is licensed under a Creative Commons Attribution 4.0 International License.

Citation in English: Science Journal of Volgograd State University. Mathematics. Physics. №1 (16) 2012 pp. 90-97

 

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