Rogozina M.V., Ionkin V.N., Ivanov A.I. Modeling the kinetics of ultrafast charge separation and charge recombination in excited zinc-porphyrins derivetes
- Details
- Hits: 1126
Abstract. The intramolecular charge separation from the second singlet excited state of Zn-porphyrin derivatives and subsequent charge recombination into the first singlet excited state have been explored. In the framework of the model considered the influence of the medium reorganization energy and dynamic properties of the solvent on the yield of products are investigated. Simulations of the chargeseparated state population dynamics allow reproducing the experimentally observed features of the kinetics in Zn-porphyrin derivatives.
Key words: second excited state, photoinduced electron transfer, nonthermal transitions, solvent relaxation, molecular switch.
Modeling the kinetics of ultrafast charge separation and charge recombination in excited zinc-porphyrins derivetes by Rogozina M.V., Ionkin V.N., Ivanov A.I. is licensed under a Creative Commons Attribution 4.0 International License.
Citation in English: Science Journal of Volgograd State University. Mathematics. Physics. №1 (16) 2012 pp. 90-97