Shcherbakova Е.V., Кazyanova М.V., Мikhailova V.А. Torsial oscillator effect on the probability of nonthermal electron transfer

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Scherbakova Ekaterina Valerievna

Student, Department of Theoretical Physics and Wave Phenomena, Volgograd State University
Prosp. Universitetsky, 100, 400062 Volgograd, Russian Federation

Kazyanova Margarita Vladimirovna

Student, Department of Theoretical Physics and Wave Phenomena, Volgograd State University
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Prosp. Universitetsky, 100, 400062 Volgograd, Russian Federation

Mikhailova Valentina Alexandrovna

Doctor of Physical and Mathematical Sciences, Professor, Department of Theoretical Physics and Wave Phenomena, Volgograd State University
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Prosp. Universitetsky, 100, 400062 Volgograd, Russian Federation

Abstract. Taking into account the deviation from the Condon approximation the influence of torsial mode on the nonthermal electron transfer dynamics is studied. Within the framework of the second-order time-dependent perturbation on the electronic coupling an analytical expression for probability of the nonthermal electron transfer from excited donor-acceptor systems is derived.

Key words: photoinduced electron transfer reaction, Condon approximation, donor-acceptor complex.

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Torsial oscillator effect on the probability of nonthermal electron transfer by Shcherbakova Е.V., Кazyanova М.V., Мikhailova V.А. is licensed under a Creative Commons Attribution 4.0 International License.

Citation in English: Science Journal of Volgograd State University. Mathematics. Physics. №1 (14) 2011 pp. 107-112

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